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A Comprehensive Review of HCN-Derived Polymers

Identificadores del recurso

Processes 9(4): 597(2021)

https://www.mdpi.com/2227-9717/9/4/597

http://hdl.handle.net/20.500.12666/586

10.3390/pr9040597

2227-9717

Procedencia

(Digital.INTA - Repositorio institucional del INTA)

Ficha

Título:: A Comprehensive Review of HCN-Derived Polymers
Tema:: HCN- derived polymers; Cyanide chemistre; Prebiotic chemistry; Multifunctional materials; 2D materials
Descripción:: HCN-derived polymers are a heterogeneous group of complex substances synthesized from pure HCN; from its salts; from its oligomers, specifically its trimer and tetramer, amino-nalono-nitrile (AMN) and diamino-maleo-nitrile (DAMN), respectively; or from its hydrolysis products, such as formamide, under a wide range of experimental conditions. The characteristics and properties of HCN-derived polymers depend directly on the synthetic conditions used for their production and, by extension, their potential applications. These puzzling systems have been known mainly in the fields of prebiotic chemistry and in studies on the origins of life and astrobiology since the first prebiotic production of adenine by Oró in the early years of the 1960s. However, the first reference regarding their possible role in prebiotic chemistry was mentioned in the 19th century by Pflüger. Currently, HCN-derived polymers are considered keys in the formation of the first and primeval protometabolic and informational systems, and they may be among the most readily formed organic macromolecules in the solar system. In addition, HCN-derived polymers have attracted a growing interest in materials science due to their potential biomedical applications as coatings and adhesives; they have also been proposed as valuable models for multifunctional materials with emergent properties such as semi-conductivity, ferroelectricity, catalysis and photocatalysis, and heterogeneous organo-synthesis. However, the real structures and the formation pathways of these fascinating substances have not yet been fully elucidated; several models based on either computational approaches or spectroscopic and analytical techniques have endeavored to shed light on their complete nature. In this review, a comprehensive perspective of HCN-derived polymers is presented, taking into account all the aspects indicated above.; M.R.-B., C.P.F. and E.M.-M. used the research facilities of the Centro de As trobiología (CSIC-INTA) and were supported by the Instituto Nacional de Técnica Aeroespacial “Esteban Terradas” (INTA) and by the Spanish State Research Agency (AEI) Centro de Astrobiología (CSIC-INTA), Unidad de Excelencia María de Maeztu. J.L.F. was supported by the Instituto Nacional de Técnica Aeroespacial “Esteban Terradas” (INTA). C.P.F. Ph-D MINECO financial support reference PRE2018-085781.; Peerreview
Idioma:: English
Autor/Productor:: Ruiz Bermejo, M.; De la Fuente, J. L.; Pérez Fernández, C.; Mateo Martí, Eva
Editor:: Multidisciplinary Digital Publishing Institute (MDPI)
Otros colaboradores/productores:: Unidad de Excelencia Científica María de Maeztu del Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737; Ruiz Bermejo, M. [0000-0002-8059-1335]; Mateo Martí, E. [0000-0003-4709-4676]
Derechos:: Attribution-NonCommercial-NoDerivatives 4.0 International; https://creativecommons.org/licenses/by-nc-nd/4.0/; info:eu-repo/semantics/openAccess
Fecha:: 2022-02-15T14:20:05Z; 2021-03-29
Tipo de recurso:: info:eu-repo/semantics/article; info:eu-repo/semantics/publishedVersion; http://purl.org/coar/resource_type/c_6501
Formato:: application/pdf

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1. < dc:title > A Comprehensive Review of HCN-Derived Polymers </ dc:title >
2. < dc:creator > Ruiz Bermejo, M. </ dc:creator >
3. < dc:creator > De la Fuente, J. L. </ dc:creator >
4. < dc:creator > Pérez Fernández, C. </ dc:creator >
5. < dc:creator > Mateo Martí, Eva </ dc:creator >
6. < dc:contributor > Unidad de Excelencia Científica María de Maeztu del Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737 </ dc:contributor >
7. < dc:contributor > Ruiz Bermejo, M. [0000-0002-8059-1335] </ dc:contributor >
8. < dc:contributor > Mateo Martí, E. [0000-0003-4709-4676] </ dc:contributor >
9. < dc:subject > HCN- derived polymers </ dc:subject >
10. < dc:subject > Cyanide chemistre </ dc:subject >
11. < dc:subject > Prebiotic chemistry </ dc:subject >
12. < dc:subject > Multifunctional materials </ dc:subject >
13. < dc:subject > 2D materials </ dc:subject >
14. < dc:description > HCN-derived polymers are a heterogeneous group of complex substances synthesized from pure HCN; from its salts; from its oligomers, specifically its trimer and tetramer, amino-nalono-nitrile (AMN) and diamino-maleo-nitrile (DAMN), respectively; or from its hydrolysis products, such as formamide, under a wide range of experimental conditions. The characteristics and properties of HCN-derived polymers depend directly on the synthetic conditions used for their production and, by extension, their potential applications. These puzzling systems have been known mainly in the fields of prebiotic chemistry and in studies on the origins of life and astrobiology since the first prebiotic production of adenine by Oró in the early years of the 1960s. However, the first reference regarding their possible role in prebiotic chemistry was mentioned in the 19th century by Pflüger. Currently, HCN-derived polymers are considered keys in the formation of the first and primeval protometabolic and informational systems, and they may be among the most readily formed organic macromolecules in the solar system. In addition, HCN-derived polymers have attracted a growing interest in materials science due to their potential biomedical applications as coatings and adhesives; they have also been proposed as valuable models for multifunctional materials with emergent properties such as semi-conductivity, ferroelectricity, catalysis and photocatalysis, and heterogeneous organo-synthesis. However, the real structures and the formation pathways of these fascinating substances have not yet been fully elucidated; several models based on either computational approaches or spectroscopic and analytical techniques have endeavored to shed light on their complete nature. In this review, a comprehensive perspective of HCN-derived polymers is presented, taking into account all the aspects indicated above. </ dc:description >
15. < dc:description > M.R.-B., C.P.F. and E.M.-M. used the research facilities of the Centro de As trobiología (CSIC-INTA) and were supported by the Instituto Nacional de Técnica Aeroespacial “Esteban Terradas” (INTA) and by the Spanish State Research Agency (AEI) Centro de Astrobiología (CSIC-INTA), Unidad de Excelencia María de Maeztu. J.L.F. was supported by the Instituto Nacional de Técnica Aeroespacial “Esteban Terradas” (INTA). C.P.F. Ph-D MINECO financial support reference PRE2018-085781. </ dc:description >
16. < dc:description > Peerreview </ dc:description >
17. < dc:date > 2022-02-15T14:20:05Z </ dc:date >
18. < dc:date > 2022-02-15T14:20:05Z </ dc:date >
19. < dc:date > 2021-03-29 </ dc:date >
20. < dc:type > info:eu-repo/semantics/article </ dc:type >
21. < dc:type > info:eu-repo/semantics/publishedVersion </ dc:type >
22. < dc:type > http://purl.org/coar/resource_type/c_6501 </ dc:type >
23. < dc:identifier > Processes 9(4): 597(2021) </ dc:identifier >
24. < dc:identifier > https://www.mdpi.com/2227-9717/9/4/597 </ dc:identifier >
25. < dc:identifier > http://hdl.handle.net/20.500.12666/586 </ dc:identifier >
26. < dc:identifier > 10.3390/pr9040597 </ dc:identifier >
27. < dc:identifier > 2227-9717 </ dc:identifier >
28. < dc:language > eng </ dc:language >
29. < dc:rights > Attribution-NonCommercial-NoDerivatives 4.0 International </ dc:rights >
30. < dc:rights > https://creativecommons.org/licenses/by-nc-nd/4.0/ </ dc:rights >
31. < dc:rights > info:eu-repo/semantics/openAccess </ dc:rights >
32. < dc:format > application/pdf </ dc:format >
33. < dc:publisher > Multidisciplinary Digital Publishing Institute (MDPI) </ dc:publisher >
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