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A Comparative Study on HCN Polymers Synthesized by Polymerization of NH4CN or Diaminomaleonitrile in Aqueous Media: New Perspectives for Prebiotic Chemistry and Materials Science

Identificadores del recurso

Chemistry: A European Journal 25: 11437-11455(2019)

0947-6539

https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201901911

http://hdl.handle.net/20.500.12666/367

10.1002/chem.201901911

1521-3765

http://dx.doi.org/10.13039/501100011033

Procedencia

(Digital.INTA - Repositorio institucional del INTA)

Ficha

Título:: A Comparative Study on HCN Polymers Synthesized by Polymerization of NH4CN or Diaminomaleonitrile in Aqueous Media: New Perspectives for Prebiotic Chemistry and Materials Science
Tema:: Prebiotic chemistry; Polymerization; HCN polymers; Structure elucidation; Polymers
Descripción:: HCN polymers are a group of complex and heterogeneous substances that are widely known in the fields of astrobiology and prebiotic chemistry. In addition, they have recently received considerable attention as potential functional material coatings. However, the real nature and pathways of formation of HCN polymers remain open questions. It is well established that the tuning of macromolecular structures determines the properties and practical applications of a polymeric material. Herein, different synthetic conditions were explored for the production of HCN polymers from NHCN or diaminomaleonitrile in aqueous media with different concentrations of the starting reactants and several reaction times. By using a systematic methodology, both series of polymers were shown to exhibit similar, but not identical, spectroscopic and thermal fingerprints, which resulted in a clear differentiation of their morphological and electrochemical properties. New macrostructures are proposed for HCN polymers, and promising insights are discussed for prebiotic chemistry and materials science on the basis of the experimental results.; The authors used the research facilities of the Centro de Astrobiología (CAB) and were supported by the Instituto Nacional de Técnica Aeroespacial “Esteban Terradas” (INTA) and by the Spanish Ministerio de Ciencia, Innovacijn y Universidades ESP2017-89053-C2-2-P. Additionally, the authors are grateful to Ma Teresa Fernández for recording the FTIR spectra and XRD and Rosana Ramírez for the SEM images. J.C.-G. acknowledges the Ramjn y Cajal contract (RYC-2015-17722); With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737); Peer review
Idioma:: English
Relación:: info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ESP2017-89053-C2-2-P/ES/QUIMICA PREBIOTICA: UNA PLATAFORMA EXPERIMENTAL PARA LA EXPLORACION DE HABITABILIDAD EN LUNAS HELADAS DEL SISTEMA SOLAR/; info:eu-repo/grantAgreement/MINECO//RYC-2015-17722
Autor/Productor:: Ruiz Bermejo, M.; De la Fuente, J. L.; Carretero González, J.; García Fernández, L.; Rosa Aguilar, M.
Editor:: Chemistry Europe: European Chemical Societies Publishing
Otros colaboradores/productores:: Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737; Agencia Estatal de Investigación (AEI)
Fecha:: 2021-04-14T12:27:22Z; 2019-08-02
Tipo de recurso:: info:eu-repo/semantics/article; info:eu-repo/semantics/publishedVersion; http://purl.org/coar/resource_type/c_2df8fbb1
Formato:: application/pdf

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1. < dc:title > A Comparative Study on HCN Polymers Synthesized by Polymerization of NH4CN or Diaminomaleonitrile in Aqueous Media: New Perspectives for Prebiotic Chemistry and Materials Science </ dc:title >
2. < dc:creator > Ruiz Bermejo, M. </ dc:creator >
3. < dc:creator > De la Fuente, J. L. </ dc:creator >
4. < dc:creator > Carretero González, J. </ dc:creator >
5. < dc:creator > García Fernández, L. </ dc:creator >
6. < dc:creator > Rosa Aguilar, M. </ dc:creator >
7. < dc:contributor > Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737 </ dc:contributor >
8. < dc:contributor > Agencia Estatal de Investigación (AEI) </ dc:contributor >
9. < dc:subject > Prebiotic chemistry </ dc:subject >
10. < dc:subject > Polymerization </ dc:subject >
11. < dc:subject > HCN polymers </ dc:subject >
12. < dc:subject > Structure elucidation </ dc:subject >
13. < dc:subject > Polymers </ dc:subject >
14. < dc:description > HCN polymers are a group of complex and heterogeneous substances that are widely known in the fields of astrobiology and prebiotic chemistry. In addition, they have recently received considerable attention as potential functional material coatings. However, the real nature and pathways of formation of HCN polymers remain open questions. It is well established that the tuning of macromolecular structures determines the properties and practical applications of a polymeric material. Herein, different synthetic conditions were explored for the production of HCN polymers from NHCN or diaminomaleonitrile in aqueous media with different concentrations of the starting reactants and several reaction times. By using a systematic methodology, both series of polymers were shown to exhibit similar, but not identical, spectroscopic and thermal fingerprints, which resulted in a clear differentiation of their morphological and electrochemical properties. New macrostructures are proposed for HCN polymers, and promising insights are discussed for prebiotic chemistry and materials science on the basis of the experimental results. </ dc:description >
15. < dc:description > The authors used the research facilities of the Centro de Astrobiología (CAB) and were supported by the Instituto Nacional de Técnica Aeroespacial “Esteban Terradas” (INTA) and by the Spanish Ministerio de Ciencia, Innovacijn y Universidades ESP2017-89053-C2-2-P. Additionally, the authors are grateful to Ma Teresa Fernández for recording the FTIR spectra and XRD and Rosana Ramírez for the SEM images. J.C.-G. acknowledges the Ramjn y Cajal contract (RYC-2015-17722); With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737) </ dc:description >
16. < dc:description > Peer review </ dc:description >
17. < dc:date > 2021-04-14T12:27:22Z </ dc:date >
18. < dc:date > 2021-04-14T12:27:22Z </ dc:date >
19. < dc:date > 2019-08-02 </ dc:date >
20. < dc:type > info:eu-repo/semantics/article </ dc:type >
21. < dc:type > info:eu-repo/semantics/publishedVersion </ dc:type >
22. < dc:type > http://purl.org/coar/resource_type/c_2df8fbb1 </ dc:type >
23. < dc:identifier > Chemistry: A European Journal 25: 11437-11455(2019) </ dc:identifier >
24. < dc:identifier > 0947-6539 </ dc:identifier >
25. < dc:identifier > https://chemistry-europe.onlinelibrary.wiley.com/doi/full/10.1002/chem.201901911 </ dc:identifier >
26. < dc:identifier > http://hdl.handle.net/20.500.12666/367 </ dc:identifier >
27. < dc:identifier > 10.1002/chem.201901911 </ dc:identifier >
28. < dc:identifier > 1521-3765 </ dc:identifier >
29. < dc:identifier > http://dx.doi.org/10.13039/501100011033 </ dc:identifier >
30. < dc:language > eng </ dc:language >
31. < dc:relation > info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ESP2017-89053-C2-2-P/ES/QUIMICA PREBIOTICA: UNA PLATAFORMA EXPERIMENTAL PARA LA EXPLORACION DE HABITABILIDAD EN LUNAS HELADAS DEL SISTEMA SOLAR/ </ dc:relation >
32. < dc:relation > info:eu-repo/grantAgreement/MINECO//RYC-2015-17722 </ dc:relation >
33. < dc:rights > Copyright © 1999-2022 John Wiley & Sons, Inc. All rights reserved </ dc:rights >
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35. < dc:format > application/pdf </ dc:format >
36. < dc:publisher > Chemistry Europe: European Chemical Societies Publishing </ dc:publisher >
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